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1.
When faced with a false generalization and a counterexample, what types of claims do prospective K-8 teachers make, and what factors influence the type and prudence of their claims relative to the data, observations, and arguments reported? This article addresses that question. Responses to refutation tasks and cognitive interviews were used to explore claiming. It was found that prospective K-8 teachers’ claiming can be influenced by knowledge of argumentation; knowledge and use of the mathematical practice of exception barring; perceptions of the task; use of natural language; knowledge of, use of, and skill with the mathematics register; and abilities to technically handle data or conceptual insights. A distinction between technical handlings for developing claims and technical handlings for supporting claims was made. It was found that prudent claims can arise from arguer-developed representations that afford conceptual insights, even when searching for support for a different claim. 相似文献
2.
Jyoti Kannoujia Pavan Kumar Bangalore Srinivas Kantevari Prabhakar Sripadi 《Journal of mass spectrometry : JMS》2020,55(10)
The HPLC‐DAD and GC/MS methods were successfully used for the identification and characterization of the impurities in an agrochemical insecticide, bifenthrin technical. Three impurities ranging from 0.175%–0.541% were detected by the HPLC‐DAD method. The LC/MS technique with ESI or APCI source failed to detect the impurities detected by HPLC‐DAD, due to lack of ionization in ESI or APCI. The three impurities were enriched by prep‐HPLC, and then their structures were elucidated based on the GC/EIMS and CIMS data. The EI mass spectra of bifenthrin and its impurities displayed molecular ion and provided structure indicative fragment ions; the CIMS data further confirmed their molecular weight. The identity of the impurity 1 was further confirmed by the synthesis of the authentic sample followed by NMR and GC/MS data. 相似文献
3.
Viktor Bezugly Pawel Wielgus Miroslav Kohout Frank R. Wagner 《Journal of computational chemistry》2010,31(7):1504-1519
Electron localizability indicators based on the parallel‐spin electron pair density (ELI–D) and the antiparallel‐spin electron pair density (ELIA) are studied for the correlated ground‐state wavefunctions of Li2, Be2, B2, and C2 diatomic molecules. Different basis sets and reference spaces are used for the multireference configuration interaction method following the complete active space calculations to investigate the local effect of electron correlation on the extent of electron localizability in position space determined by the two functionals. The results are complemented by calculations of effective bond order, vibrational frequency, and Laplacian of the electron density at the bond midpoint. It turns out that for Li2, B2, and C2 the reliable topology of ELI–D is obtained only at the correlated level of theory. © 2009 Wiley Periodicals, Inc. J Comput Chem, 2010 相似文献
4.
一类重尾风险因子的模拟及其投资高风险值和置信区间的估计 总被引:2,自引:0,他引:2
由于金融市场中的日周期或短周期对数回报率的样本数据多数呈现胖尾分布,于是现有的正态或对数正态分布模型都在不同程度上失效,为了准确模拟这种胖尾分布和提高投资风险估计及金融管理,本文引进了一种可根据实际金融市场数据作出调正的蒙特卡洛模拟方法.这个方法可以有效地复制金融产品价格的日周期对数回报率数据的胖尾分布.结合非参数估计方法,利用该模拟方法还得到投资高风险值以及高风险置信区间的准确估计。 相似文献
5.
6.
CI战略成功导入的关键,是对企业内部CI作业群体的行为进行系统、科学的管理。本文在首先提出企业内部群体行为管理假说的基础上,借鉴系统科学的相关思想,就CI作业过程中群体行为管理的基本方法,作了较为深入,全面的探讨。 相似文献
7.
Summary Complete active space SCF, CASSCF, and contracted CI calculations have been performed on the -bonded complex between ethylene and an iron atom. An extended basis set of the ANO type was used, which included polarization functions on all centers. The results indicate an attractive interaction between Fe 5
F(d7s) and ethylene, with an estimated binding energy of 14 kcal/mol. The low spin complex arising from Fe 3
F(d7s) was found to be bound with 18 kcal/mol. Both these potential minima are, however, above the ground state of the iron atom. It is concluded that the interaction between atomic ground state iron and ethylene is not of the normal -bonded type, but is dominated by dispersion forces. A preliminary study showed this interaction to be almost isotropic, with no preferred site for the iron atom. 相似文献
8.
Summary A comprehensive study of the binary association complexes B2H6 and AlBH6 has been performed by ab initio molecular orbital theory. Reliable formation enthalpies can be computed only be extended basis sets and a reasonably complete account of correlation. The greater stability towards neutral dissociation of AlBH6 with respect to B2H6 obtained at the Hartree-Fock level employing the 6-21G* basis set ( 10 kcal/mol) is reduced to only 2 kcal/mol when the basis set is sufficiently saturated and correlation energy properly included. The value of the activation energy for hydrogen scrambling in AlBH6 is much less sensitive to the method used, although correlation still plays a significant rôle reducing the potential energy barrier from 11.4 to 7.7 kcal/mol. 相似文献
9.
Summary Valence Full Configuration Interaction (FCI) calculations are reported for the N2 molecule with a 4s3p triple-zeta basis set at different distances. The size of the FCI space is more than 225 000 000 symmetry-adapted Slater
determinants. The computation requires about 1400 s of c.p.u. time per iteration on a CRAY C90, and is one of the largest
FCI calculations ever converged. Our results, as is in general the case for FCI computations, can be used to test the performance
of approximated methods used to study electronic correlation in molecules.
The authors of this paper have agreed to not receive the proofs for correction. 相似文献
10.
干旱历时和干旱强度是影响干旱灾害风险的主要因素。根据干旱灾害发生的极端过程特点,用极值理论刻画干旱灾害风险两个特征变量的边缘分布,用Archimedes Copula函数捕捉旱灾风险两个特征变量之间的极值相依结构,本文构建的基于Copula-EVT的旱灾风险评估模型较好地反映了旱灾形成的极端过程和影响因子。实证分析以淮河流域蚌埠站为例,证实了ClaytonCopula-EVT模型能较好地拟合蚌埠站干旱灾害风险的历史经验分布,计算得出:蚌埠站干旱历时大于5个月,干旱强度超过7.45的极端干旱灾害风险概率为3%,重现期T_∩(t,d)为32.4年,对干旱历时和干旱强度的条件重现期研究得出干旱强度的取值对干旱灾害风险重现期的影响较大。 相似文献